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It depends on the type of use you plan for your butcher-block top and the look you want.

If it is a statement piece and not intended for high use, almost any finish would work. General Finishes Arm-R-Seal Topcoat is a good choice. If you intend to prep or chop food General Finishes Butcher Block Oil should be applied.

You can reduce the glossiness of a sheen several ways.

1. Apply a flatter sheen over a glossier sheen, such as Satin over Semi-gloss. Be sure to observe proper dry times. If you are applying over an existing finish, be sure to prep sand and clean first. 
2. If using General Finishes Arm-R-Seal, you can intermix Satin and Semi-Gloss to create a sheen that will softly mute the glossiness.
3. Another option is to rub the surface down with 0000 steel wool and orange oil or any similar lubricant such as Butcher Block Oil.

Some pieces of wood contain a lot of oil and walnut can be finicky.

The oil in the walnut wood may be causing the problem you've described - a longer dry time might have been needed over an oily wood. If the wood does not dry over the next few days then it may be necessary to sand down and start over.

Unfortunately, if the first coat does not dry, the second will never dry.