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What is the definition of VOC?

According to the EPA "Volatile organic compounds (VOC) means any compound of carbon, excluding carbon monoxide, carbon dioxide, carbonic acid, metallic carbides or carbonates, and ammonium carbonate, which participates in atmospheric photochemical reactions." These carbon-containing chemicals that are labeled volatile because they easily become gases that enter the atmosphere. They include both human-made and naturally occurring chemical compounds produced by plant and animal processes.

Gravity can cause some solids to settle on the bottom of the can and slight separation on the top. This is normal.

If working with older paint, use a paint mixing attachment on a drill to reincorporate the solids. If the solids dissolve and the clumps smooth out after mixing from the bottom, the product is in good condition. 

If your water based product has large chunks that cannot be incorporated by stirring, the product has frozen and can no longer be used.